<?php
$namen[] = "1.php";
$namen[] = "2.php";
$namen[] = "3.php";
$namen[] = "4.php";
$namen[] = "5.php";
$namen[] = "6.php";

$pfade[] = "c:\\dir\\blub1\\";
$pfade[] = "c:\\dir\\blub2\\";
$pfade[] = "c:\\dir\\blub3\\";
$pfade[] = "c:\\dir\\blub4\\";
$pfade[] = "c:\\dir\\blub5\\";
$pfade[] = "c:\\dir\\blub6\\";


for($i=0;$i<count($namen);$i++)
{
$tpl_arr[$namen[$i]] = $pfade[$i];
}

echo '<pre>';
var_dump($tpl_arr);
echo '</pre>';

?>

array(6) {
  ["1.php"]=>
  string(13) "c:\dir\blub1\"
  ["2.php"]=>
  string(13) "c:\dir\blub2\"
  ["3.php"]=>
  string(13) "c:\dir\blub3\"
  ["4.php"]=>
  string(13) "c:\dir\blub4\"
  ["5.php"]=>
  string(13) "c:\dir\blub5\"
  ["6.php"]=>
  string(13) "c:\dir\blub6\"
}